Wednesday, May 23, 2012


Dalam 100 mL larutan jenuh Ca3(PO4)2 trdpt 0,01 mg ion Ca2+. Tentukan harga Ksp Ca3(PO4)2 tsb!
M Ca ^2= 0,01/1000 X 1000/100= 10^-4
Ca3(PO4)2==== 3Ca^2+      +  2(PO4)^3-
                        Jika 1 0^-4          2/3 x   1 0^-4
Ksp=[ Ca^2+ ] ^3  . [(PO4)^3-   ]^2
            =      1 0^-4 ^3 x (2/3 1 0^-4)^2

2) suatu basa M(OH)2 mmpunyai harga Ksp= 1x10-15. Apakah trbntuk endapan M(OH)2 apabila 50mL larutan MSO4 0,01M dicampur dgn 50mL larutan NH3 0,1 M ?
N MSO4= M.V= 50.0,01= 0,5 M.MOL
                MSO4à M^2+   + SO4 ^2-
                0,5           0,5 MMOL
                [M^2+   ] = 0,5/Vol campuran = 0,5/100= 0,005 M
Pengenceran ammonia
M 1 . V 1  = M2.V2   =.50.0,1 = 100. M2
                                M 2= 0,005 M
[0H ^-] = Kb.[Bs] = √2.10^-5  X 5.10^-3 = 3.10^-4
Q =[ M^2+   ]. [OH^-]^2= 5.10^-3X (3.10^-4)^2 =4,5. 10^-10
Karena Q lebih besar dari Ksp maka mengendap

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